Abstract
We evaluated condition-normalized ranking for electrocatalytic screening under 28% current-density variation. A deterministic paired simulation generated 72 cases and preserved a upper-severity quartile. Mean selectivity score changed from 0.498 to 0.536; the paired difference was +0.038 (95% interval +0.036 to +0.040). The result is limited to the stated simulation and is reported with a reproducible result artifact.
References
Xia, F., Li, B., Liu, Y., Tan, H., An, B., Gao, S., Marks, T.-J., & Cheng, Y. (2024). Critical Roles of Chalcogenide Anion on Strengthening Stability of Ni 2 Mo 6 Te 8 for Almost Exclusive Electrocatalysts Nitrate to Ammonia Conversion. Advanced Functional Materials, 34(14), 2312079. https://doi.org/10.1002/adfm.202312079
Han, C., Sun, L., Han, S., & Liu, B. (2025). Stabilizing Hydrogen Radicals in Two-Dimensional Cobalt-Copper Mesoporous Nanoplates for Complete Nitrate Reduction Electrocatalysis to Ammonia. Angewandte Chemie International Edition, 64(5), e202416910. https://doi.org/10.1002/anie.202416910
Yin, Q., Hu, S., Liu, J., & Zhou, H. (2022). Electrochemical ammonia synthesis via nitrate reduction on perovskite La x FeO 3- delta with enhanced efficiency by oxygen vacancy engineering. Sustainable Energy & Fuels, 6(20), 4716-4725. https://doi.org/10.1039/d2se00997h
zhao, J., Song, X. S., Jiao, D., & Liu, S. (2026). CeOx-Integrated Cu Dual Active Sites for Efficient Electrocatalytic Nitrate Reduction to Ammonia. https://doi.org/10.2139/ssrn.6843032
Lori, O., & Elbaz, L. (2022). Enhanced Oxygen Reduction and Fuel Cell Performance and Durability of Ultra-Low Loading Pt-Supported High Surface Area Titanium Nitro-Carbide. https://doi.org/10.2139/ssrn.4267990
Huang, P. W., Song, H., Yoo, J., Chipoco Haro, D., Lee, H. M., Medford, A., & Hatzell, M. (2023). Electrochemical nitrate reduction to ammonia in a BPM-MEA system. https://doi.org/10.26434/chemrxiv-2023-kkmsm
Mandal, S., Kawawaki, T., Biswas, S., & Negishi, Y. (2026). Atomically precise metal nanoclusters in nitrate-to-ammonia electrocatalysis. https://doi.org/10.26434/chemrxiv.15005808/v1
Powar, N., & Banerjee, P. (2025). Sodium Substitution Effects on Ammonia Selectivity of Cu₃N Nanocrystals for Electrochemical Nitrate Reduction. https://doi.org/10.26434/chemrxiv-2025-3zqxg
Zhao, K., Sun, Y., Yang, X., Pu, J., Shi, Y., Chen, P., Yang, J., & Yu, F. (2026). Nonmetallic Si Doping Constructs Cu 2 O/Co-O-Si Tandem Sites for Neutral Nitrate Reduction Electrocatalysis Toward Ammonia Recovery and Energy-Integrated Applications. Angewandte Chemie, e9522099. https://doi.org/10.1002/ange.9522099
Qin, L., Tong, Z., Chen, G., Zhou, Q., Liu, C., Wu, Y., Ye, M., Jiang, B., Tan, Y., Huang, G., Fan, G., & Wu, K. (2026). Synergistic effect of oxygen vacancies and oxygen-bridged multi-interface sites for high-performance electrocatalytic nitrate reduction to ammonia. Nano Research, 19(8), 94908769. https://doi.org/10.26599/nr.2026.94908769
